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Combating sulphuric acid corrosion at wastewater plants: Graz scientists develop new solution

Writing in Water Research, researchers from TU Graz and the University of Graz discuss new materials that prevent damage from microbial induced concrete corrosion.

A male hand holds a concrete part damaged by microbial induced concrete corrosion (MICC); a centimetre-thick deposit has formed on the part.
A man in a protective suit in a concrete shaft.
A concrete part damaged by microbial induced concrete corrosion
Microbial induced concrete corrosion (MICC) causes massive damage to wastewater plants. Researchers from Graz present a new solution against the sulphuric acid attack. © TU Graz

More pictures available at the end of the text

Wastewater systems are integral to infrastructure in every community. In an ideal world, they operate smoothly and are long-lasting. But biogenic transformation processes in sewage and water treatment systems are a “natural enemy” of conventional plants, frequently causing damage to concrete and metal elements that is expensive to repair. As a result, it is not uncommon for wastewater systems to have a lifespan of under ten years, before they need to be refurbished or individual components replaced. Toxic gases released during biogenic processes, such as hydrogen sulphide, also pose a significant health risk, causing a range of symptoms from irritation to respiratory failure and death.

Writing in the journal Water Research, an interdisciplinary group of researchers from TU Graz and the University of Graz has outlined strategies aimed at preventing what is termed microbial induced concrete corrosion (MICC). The research team comprises two TU Graz staff members – Cyrill Grengg of the Institute of Applied Geosciences and Florian Mittermayr of the Institute of Technology and Testing of Construction Materials – as well as Günther Koraimann of the University of Graz’s Institute of Molecular Biosciences.

Microbial induced concrete corrosion: turning a blind eye not the answer

Cyrill Grengg of the Institute of Applied Geosciences at TU Graz explained: “MICC often corrodes the conventional types of concrete used in wastewater treatment plants at a rate of a centimetre or more per year. Accordingly, the concrete elements can be destroyed in a matter of only a few years, causing significant damage to wastewater systems.” According to the researchers, there is often a lack of awareness of these processes and the resulting threat to wastewater infrastructure and human health. “Closing the manhole covers and looking the other way is not the answer,” Grengg added. In Germany alone, the economic impact of wastewater system repairs is put at around EUR 450 million per year. Although no data are currently available for Austria, the costs can be extrapolated and also applied to other European countries.

Microbial induced acid corrosion (MICC) in wastewater treatment facilities results from a sequence of biogenic sulphate reduction reactions, followed by reoxidation. Initially, sulphate in pressure pipelines or standing wastewater is reduced by bacteria under anaerobic – or oxygen-free – conditions, forming hydrogen sulphide. This pungent, highly poisonous gas escapes into the sewer air and diffuses into sewer pipes and manholes. There reoxidation by autotrophic bacteria takes place on concrete walls that do not even come into contact with wastewater. These microorganisms produce sulphuric acid which reacts with concrete construction elements. As Günther Koraimann of the Institute of Molecular Biosciences at the University of Graz, who has studied these processes in detail, explains: “This leads to the vigorous formation of a biofilm on the surface of the concrete, a reduction of the pH value to below two, in other words highly acidic, and extensive formation of new minerals, mainly in the form of gypsum. The combination of these processes results in the rapid destruction of the concrete.”

Holistic solution

The Graz-based scientists worked on a holistic solution using an interdisciplinary research approach. In-depth research into the microstructural and microbiological processes was followed by the development of new MICC-resistant materials in close collaboration with the Institute of Construction and Building Materials at TU Darmstadt. In this context, geopolymer concrete proved to be particularly well suited to withstand acid corrosion. When developing this building material, resistance to acid was an extremely desirable property, as were highly antibacteriostatic surfaces, on which the research team made significant advances – microorganisms that trigger the initial oxidation process are unable to settle on such surfaces in the first place. In turn, this prevents the formation of sulphuric acid.

Florian Mittermayr of the Institute of Technology and Testing of Construction Materials at TU Graz commented: “We achieved some very promising results with materials that have a far greater lifespan than conventional types of concrete. Use of these long-lasting materials would allow operators to refurbish damaged wastewater systems, significantly extending their service life and reducing the financial burden on local government and wastewater associations.” The researchers published their latest findings on MICC prevention in the current issue of the journal Water Research.

The province of Styria provided financial backing for the research, and is dedicated to raising awareness of this global problem among Styrian local authorities and regional wastewater associations.

This research area is anchored in the Fields of Expertise „Sustainable Systems“ and “Advanced Materials Science”, two of five research FoE of TU Graz.

Information

The research results are published in the journal Water Research

Water Research 134 (2018) 341 - 352
Advances in concrete materials for sewer systems affected by microbial induced concrete corrosion: A review

Contact

Dr. Cyrill GRENGG
TU Graz | Institute of Applied Geosciences
Mobil: +43 680 3169642 | Email: cyrill.grenggnoSpam@tugraz.at

Dr. Florian MITTERMAYR
TU Graz | Institute of Technology and Testing of Construction Materials
Tel.: +43 316 873 7159 | Email: f.mittermayrnoSpam@tugraz.at

Ao.Univ.-Prof. Dr. Günther KORAIMANN,
Uni Graz | Institute of Molecular Biosciences
Tel.: +43 316 380 5626 | Email: guenther.koraimannnoSpam@uni-graz.at

Graphic material

available free of charge at subject to citing of the stated sources (download in high resoultion by clicking on the image).
A male hand holds a concrete part damaged by microbial induced concrete corrosion (MICC); a centimetre-thick deposit has formed on the part.
A man in a protective suit in a concrete shaft.
A concrete part damaged by microbial induced concrete corrosion
In field tests researchers from TU Graz and Graz University investigated the damage caused by microbial induced concrete corrosion. © TU Graz
A male hand holds a concrete part damaged by microbial induced concrete corrosion (MICC); a centimetre-thick deposit has formed on the part.
A man in a protective suit in a concrete shaft.
A concrete part damaged by microbial induced concrete corrosion
A concrete part damaged by microbial induced concrete corrosion. © TU Graz