DiREkT - Direct reduction of iron carbonate

An alternative approach for pig iron production from mineral siderite.

The iron and steel industry is one of most relevant industrial sectors worldwide. The blast furnace process makes mainly use of hematite (Fe2O3) as primary iron source, covering about two-thirds of the global steel production. The reducing agent and primary energy source for the blast furnace process is coke. Austria and China have major mineral iron carbonate (= siderite, FeCO3) reserves, which are used as ores for iron and steel production. Siderite beneficiation is challenging, because of the low iron content of the ore compared to magnetite and hematite ores. The industrial practice is to blend siderite with other high-grade ores in the sinter plant. During the sintering process, siderite is converted to hematite through roasting in air. The sinter product is fed to the blast furnace where it is preferably reduced with coke via CO, producing at least 1.5 mole CO2 per mole of iron due to the stoichiometry of reaction. Consequently, at least 2.5 mole CO2 are emitted during the production of 1 mole of iron from iron carbonate.

Aim of this project is to develop an alternative process for pig iron production by direct reduction of siderite with hydrogen. The reduction process is followed by separation of the unconverted ore matrix (gangue) for direct use of the pig iron in the steel converter. In the ideal case of complete carbonate conversion, elemental iron is formed together with CO2, carbon monoxide (CO), methane (CH4) or higher hydrocarbons (CxHy), resulting in significant CO2 emission reduction. Technology development is based on mineral ore from the Styrian Erzberg. The process shows high potential for significant reduction of CO2 emissions and less specific energy demand.

Reactor test stand in lab scale.

Involved Organizations

  • Montanuniversität Leoben, Institut für Aufbereitung und Veredlung
  • VA Erzberg GmbH

Acknowledgements

The project is funded by the Austrian Klima- und Energiefonds in the framework of the program ‘Energieforschungsprogramm 4. Ausschreibung’ (FFG 865043). Financial support by the Klima- und Energiefonds is gratefully acknowledged.

Contact
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Susanne Lux
Ass.Prof. Priv.-Doz. Dipl.-Ing. Dr.techn.

Institut für Chemische Verfahrenstechnik und Umwelttechnik
Inffeldgasse 25/C
8010 Graz

Phone
+43 316 873 - 7476
Members
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Astrid Loder
Dipl.-Ing. BSc

Duration
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02/2018-01/2021


Link Project Description
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